Open Chemistry Journal




(Discontinued)

ISSN: 1874-8422 ― Volume 8, 2021

Design and Synthesis of a Multi Cu(II)-porphyrin Array



Virginia Gómez-Vidalesa, Andres Borja-Mirandaa, Sandra Cortez-Mayaa, Oscar Amelines-Sarriab, Margarita Riverab, Marcos Martínez-Garcíaa, *
a Instituto de Química, Universidad Nacional Autónoma de México, Ciudad Universitaria, Mexico city, Mexico
b Instituto de Física, Universidad Nacional Autónoma de México, Ciudad Universitaria, Mexico city, Mexico

Abstract

A new class of porphyrin array was synthesized. The Cu(II) porphyrin-PAMAM-Cu(II) porphyrin was obtained in good yields. The EPR studies showed that all porphyrins obtained have signals of a copper complex with planar geometry, and no variation in the tetrahedral distortion of the porphyrin ring was observed. The UV-vis and emission studies showed that the intensity of the signal increased due to the presence of 5 porphyrin moieties in the structure. In order to further characterize this molecule, thin films were prepared by using the thermal evaporation method. The morphology of the film showed a homogeneous structure while conductivity measurements exhibit a good conductive response.

Keywords: Conductivity, EPR, multi-porphyrin array, porphyrin.


Article Information


Identifiers and Pagination:

Year: 2016
Volume: 3
First Page: 25
Last Page: 34
Publisher Id: CHEM-3-25
DOI: 10.2174/1874842201603010025

Article History:

Received Date: 1/10/2015
Revision Received Date: 27/1/2016
Acceptance Date: 30/1/2016
Electronic publication date: 25/05/2016
Collection year: 2016

© Gómez-Vidales et al.; Licensee Bentham Open.

open-access license: This is an open access article licensed under the terms of the Creative Commons Attribution-Non-Commercial 4.0 International Public License (CC BY-NC 4.0) (https://creativecommons.org/licenses/by-nc/4.0/legalcode), which permits unrestricted, non-commercial use, distribution and reproduction in any medium, provided the work is properly cited.


* Address correspondence to this author at the Instituto de Química, Universidad Nacional Autónoma de México, Ciudad Universitaria, Circuito Exterior, Coyoacán, C.P. 04510, México city, México; E-mail: margar@unam.mx



Track Your Manuscript:


Endorsements



I am completely satisfied with the service I received from Bentham Science Publishers, right from the submission of our research paper in ‘Open Chemistry’ to its publication in the journal. The reviewers' and editor's comments were very helpful in improving the paper.

I take this opportunity to express my appreciation to the whole team of BSP!


Dr. Arun Kumar Sharma
Govt. P.G. College,
India


Browse Contents



Webmaster Contact: info@benthamopen.net
Copyright © 2023 Bentham Open