Table 6: Thermodynamic parameters for the decomposition reaction of copper surfactants derived from various oils.
| Compound |
Method |
Z (s-1) |
ΔS* |
ΔH* |
ΔG* |
| (J K-1 mol-1) |
(kJ mol-1) |
(kJ mol-1) |
| CG |
F.C.E. |
1.19 |
-324.22 |
51.73 |
229.55 |
| C.R.E. |
4.27 |
-237.55 |
49.83 |
180.21 |
| H.M.E. |
17.12 |
-207.45 |
52.68 |
166.25 |
| B.E. |
10.99 |
-230.34 |
59.79 |
185.87 |
| P.N.E. |
0.142 |
-266.44 |
40.69 |
186.43 |
| CS |
F.C.E. |
6.67 x 10-6
|
-309.71 |
43.72 |
213.43 |
| C.R.E. |
6.98 x 10-4
|
-310.42 |
43.98 |
214.22 |
| H.M.E. |
10.05 |
-230.8 |
32.34 |
158.83 |
| B.E. |
3.911 |
-238.86 |
33.89 |
164.62 |
| P.N.E. |
1.66 x 10-2
|
-284.85 |
31.82 |
187.45 |
| CN |
F.C.E. |
3.16 x 10-7
|
-355.02 |
57.69 |
241.32 |
| C.R.E. |
9.32 x 10-3
|
-288.82 |
56.31 |
214.62 |
| H.M.E. |
63.81 |
-215.45 |
63.48 |
181.55 |
| B.E. |
6.36 |
-234.62 |
66.27 |
194.84 |
| P.N.E. |
0.300 |
-260.06 |
73.33 |
215.82 |
| CK |
F.C.E. |
2.70 x 10-5
|
-300.73 |
38.42 |
202.96 |
| C.R.E. |
2.92 x 10-4
|
-317.76 |
40.12 |
214.26 |
| H.M.E. |
8.42 |
-232.31 |
38.93 |
166.24 |
| B.E. |
3.08 |
-240.63 |
30.09 |
161.96 |
| P.N.E. |
4.42 x 10-3
|
-295.03 |
24.98 |
186.62 |