Table 3: Selected intermolecular distances (Å) and angles (°) for naphthalene-octafluoronaphthalene, 1.a

100 K 150 K 200 K 250 K 294 [32]
< C10F8(plane)a axis 66.5(4) 66.6(4) 66.5(4) 66.6(4) 66.7
< C10H8(plane)a axis 70.3(4) 70.2(4) 70.2(4) 70.1(4) 69.9
< C10F8(plane)bc plane 30.05(4) 30.03(5) 30.2(1) 30.2(1) 30.5
< C10H8(plane)bc plane 25.85(6) 26.0(1) 26.2(1) 26.4(1) 26.7
< C10F8(plane) C10F8(plane)b 33.51(8) 33.63(7) 33.9(1) 34.1(1) 34.1
< C10H8(plane) C10H8(plane)b 30.54(6) 30.7(1) 30.9(1) 31.2(1) 31.5
C10F8(plane)···C10F8(plane) 6.704(3) 6.743(3) 6.771(3) 6.813(3) 6.847
offset C10F8···C10F8 2.919(3) 2.922(3) 2.941(3) 2.949(3) 2.954
C10H8(plane)···C10H8(plane) 6.885(3) 6.916(3) 6.947(3) 6.979(3) 7.004
Offset C10H8···C10H8 2.462(3) 2.485(3) 2.497(3) 2.529(3) 2.559
˂ C10F8(plane) C10H8(plane) 4.30(8) 4.08(6) 4.1(1) 3.9(1) 3.7
C10H8(centre)···C10F8(centre) 3.656(3) 3.675(3) 3.691(3) 3.711(3) 3.728
C10H8(centre)···C10F8(plane) 3.352(3) 3.372(3) 3.385(3) 3.407(3) 3.424
offset 1.460(3) 1.461(3) 1.471(3) 1.471(3) 1.475
C10F8(centre)···C10H8(plane) 3.442(3) 3.458(3) 3.473(3) 3.490(3) 3.502
offset 1.232(3) 1.244(3) 1.250(3) 1.262(3) 1.278
C(13)···F(4) 3.258(2) 3.282(2) 3.309(3) 3.334(3) 3.360
C(14)···F(3) 3.587(2) 3.602(2) 3.629(2) 3.648(2) 3.681
F(3)···F(4) 3.053(2) 3.067(2) 3.081(2) 3.097(2) 3.114
F(4)···F(4) 2.757(2) 2.776(2) 2.801(2) 2.828(2) 2.865
C(14)···C(14) 3.852(3) 3.876(3) 3.909(3) 3.941(3) 3.987
C(13)···C(14) 4.124(2) 4.144(2) 4.168(3) 4.193(3) 4.225
C(12)···F(5) 3.326(2) 3.349(2) 3.370(3) 3.393(3) 3.410
C(13)···F(5) 3.260(2) 3.281(2) 3.310(3) 3.331(3) 3.360
C(13)···F(2) 3.725(2) 3.751(2) 3.784(3) 3.813(3) 3.856
F(2)···F(4) 2.792(2) 2.814(2) 2.832(2) 2.857(2) 2.891
F(5)···F(4) 2.988(2) 3.005(2) 3.024(2) 3.050(2) 3.079
F(3)···F(5) 3.292(2) 3.321(2) 3.347(2) 3.382(2) 3.420

a Estimated standard deviations are given in parentheses. b The angle between the planes of the molecules of different columns.