Scheme (2) Synthetic pathways to analogs 13-14. Reagents and conditions: (a) BH3/THF, 0 oC-rt (b) TBAI, Pyridine, CH2Cl2, Tf2O, -78 oC-rt (c) NaN3, MeCN, reflux (d) PPh3, rt (e) 2-Furoic acid, HBTU, Et3N, MeCN, rt.