RESEARCH ARTICLE


Kinetics of Iron (II) Removal from Aqueous Solution Using Activated Dolomite



G.M. Walker*, G. Connor, S.J. Allen
School of Chemistry and Chemical Engineering, Queen’s University Belfast, Belfast BT9 5AG, Northern Ireland, UK


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Creative Commons License
© 2007 Walker et al.

open-access license: This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 International Public License (CC-BY 4.0), a copy of which is available at: https://creativecommons.org/licenses/by/4.0/legalcode. This license permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.

* Address correspondence to this author at the School of Chemistry and Chemical Engineering, Queen’s University Belfast, Belfast BT9 5AG, Northern Ireland, UK; Tel: +44 (0) 2890 974172; Fax: +44 (0)2890 974627; E-mail: g.walker@qub.ac.uk


Abstract

Experimental investigations were undertaken in batch kinetic systems, for the removal of iron (II) from aqueous solutions using activated dolomite. The effect of the extent dolomite activation on the dissolution of magnesium and calcium from the dolomite lattice was determined. Under optimum experimental conditions there was a direct linear relationship between magnesium dissolution and iron (II) removal from bulk solution. The experimental data were mathematically described using empirical external mass transfer and pseudo-intra-particle diffusion models. The data show conformity with a three stage process, with the iron (II) removal rate showing good correlation with external mass transfer (t < 1 min) and two rates of pseudo-intra-particle diffusion (1 < t < 90mins, and t < 90mins).